Details

Autor(en) / Beteiligte

• Kargin, Denis
• Kelemen, Zsolt
• Krekić, Kristijan
• Maurer, Martin
• Bruhn, Clemens
• Nyulászi, László
• Pietschnig, Rudolf

Titel

[3]Ferrocenophanes with the bisphosphanotetryl bridge: inorganic rings on the way to tetrylenes

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2016-01, Vol.45 (5), p.2180-2189

Ort / Verlag

England

Erscheinungsjahr

2016

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A series of [3]ferrocenophanes with functional P-E-P motifs (E = group 14 fragments) is reported. Out of these, the silicon compounds with the general formula Fe(C5H4PtBu)2SiXY (XY = Cl2, Br2, I2, H2, HCl) have been characterized by spectroscopic means and the bonding situation was analyzed using X-ray crystallography and quantum chemical calculations. Despite the two stereogenic phosphanyl centers, most of the [3]ferrocenophanes have been obtained as single isomers in the course of stereospecific reactions. The corresponding stannylene Fe(C5H4PtBu)2Sn has been obtained in the form of its dimeric adduct.