Chemical communications (Cambridge, England), 2014-09, Vol.50 (73), p.10588-10591
2014
Details
- Autor(en) / Beteiligte
- Titel
- Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP)
- Ist Teil von
- Chemical communications (Cambridge, England), 2014-09, Vol.50 (73), p.10588-10591
- Ort / Verlag
- England
- Erscheinungsjahr
- 2014
- Link zum Volltext
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- A general thermolysis reaction for the transformation of Group 1 TMP compounds (LiTMP, NaTMP, KTMP) to 1-aza-allylic TTHP derivatives is reported. TMEDA accelerates the reaction and produces the crystalline complexes [(TMEDA)LiTTHP] and [(TMEDA·NaTTHP)2]. Methane elimination during the transformational process was confirmed via TVA coupled to MS.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1359-7345eISSN: 1364-548XDOI: 10.1039/c4cc04959dTitel-ID: cdi_proquest_miscellaneous_1893881866
- Format
- –
- Schlagworte
- Alkali metals, Amides, Amides - chemistry, Coordination Complexes - chemistry, Crystal structure, Crystallography, X-Ray, Derivatives, Metals, Alkali - chemistry, Methane, Methane - chemistry, Molecular Conformation, Piperidines - chemistry, Salts - chemistry, Transformations, Utilities