Angewandte Chemie (International ed.), 2008-01, Vol.47 (11), p.2131-2134
2008
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Details
- Autor(en) / Beteiligte
- Titel
- Stable Deacon Process for HCl Oxidation over RuO2
- Ist Teil von
- Angewandte Chemie (International ed.), 2008-01, Vol.47 (11), p.2131-2134
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2008
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Selective substitution: In the oxidation of HCl with oxygen to give Cl2 and water, RuO2(110) serves as a stable, active model catalyst for the Sumitomo process (see picture; Ru in red and blue). The stability of the catalyst is related to the selective replacement of undercoordinated bridging surface O atoms (Obr) by Cl atoms (Clbr). The chlorination of RuO2(110) is self‐limiting, in that chlorine incorporation terminates when all bridging O atoms are replaced.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851, 1521-3773eISSN: 1521-3773DOI: 10.1002/anie.200705124Titel-ID: cdi_swepub_primary_oai_lup_lub_lu_se_22d7dd24_4172_49cd_969b_9d1a418c4ee3
- Format
- –
- Schlagworte
- Chemical Sciences, Deacon process, dioxide, heterogeneous catalysis, Kemi, Natural Sciences, Naturvetenskap, oxide surfaces, ruthenium, ruthenium dioxide, surface chemistry