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High‐Performance Noncovalently Fused‐Ring Electron Acceptors for Organic Solar Cells Enabled by Noncovalent Intramolecular Interactions and End‐Group Engineering
Ist Teil von
Angewandte Chemie (International ed.), 2021-05, Vol.60 (22), p.12475-12481
Auflage
International ed. in English
Ort / Verlag
Germany: Wiley Subscription Services, Inc
Erscheinungsjahr
2021
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Noncovalently fused‐ring electron acceptors (NFREAs) have attracted much attention in recent years owing to their advantages of simple synthetic routes, high yields and low costs. However, the efficiencies of NFREAs based organic solar cells (OSCs) are still far behind those of fused‐ring electron acceptors (FREAs). Herein, a series of NFREAs with S⋅⋅⋅O noncovalent intramolecular interactions were designed and synthesized with a two‐step synthetic route. Upon introducing π‐extended end‐groups into the backbones, the electronic properties, charge transport, film morphology, and energy loss were precisely tuned by fine‐tuning the degree of multi‐fluorination. As a result, a record PCE of 14.53 % in labs and a certified PCE of 13.8 % for NFREAs based devices were obtained. This contribution demonstrated that combining the strategies of noncovalent conformational locks and π‐extended end‐group engineering is a simple and effective way to explore high‐performance NFREAs.
We constructed a series of noncovalently fused‐ring electron acceptors (NFREAs) with S⋅⋅⋅O noncovalent intramolecular interactions. Combining the strategies of noncovalent conformational locks and π‐extended end‐group engineering, a record PCE of 14.53 % in labs and a certified PCE of 13.8 % for NFREAs based devices were achieved.