Details

Autor(en) / Beteiligte

• Gansäuer, Andreas
• Hildebrandt, Sven

Titel

Reductive Electron Transfer in the Synthesis of Heterocycles

Ist Teil von

• Free-Radical Synthesis and Functionalization of Heterocycles, 2018, Vol.54, p.253-283

Ort / Verlag

Switzerland: Springer International Publishing AG

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• This review summarizes the concepts involved in reductive electron transfer to organic substrates and subsequent heterocycle formation via radical intermediates. Furthermore, representative examples of existing methodologies are discussed that elucidate the scope and applicability of reductive electron transfer in heterocycle synthesis from simple five- and six-membered ring formation to complex structural motifs. The discussion mainly focuses on low-valent metal complexes as well as selected examples of organic ground-state reductants.