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Recent advances in C(sp)-N bond formation metallaphoto-redox catalysis
Ist Teil von
Chemical communications (Cambridge, England), 2024-06, Vol.6 (5), p.634-6361
Erscheinungsjahr
2024
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The C(sp
3
)-N bond is ubiquitous in natural products, pharmaceuticals, biologically active molecules and functional materials. Consequently, the development of practical and efficient methods for C(sp
3
)-N bond formation has attracted more and more attention. Compared to the conventional ionic pathway-based thermal methods, photochemical processes that proceed through radical mechanisms by merging photoredox and transition-metal catalyses have emerged as powerful and alternative tools for C(sp
3
)-N bond formation. In this review, recent advances in the burgeoning field of C(sp
3
)-N bond formation
via
metallaphotoredox catalysis have been highlighted. The contents of this review are categorized according to the transition metals used (copper, nickel, cobalt, palladium, and iron) together with photocatalysis. Emphasis is placed on methodology achievements and mechanistic insight, aiming to inspire chemists to invent more efficient radical-involved C(sp
3
)-N bond-forming reactions.
In this review, the state-of-the-art advances in radical-involved C(sp
3
)-N bond formation
via
metallaphotoredox catalysis have been highlighted, which are organized according to different catalytic modes, reaction types, and substrate classes.
Sprache
–
Identifikatoren
ISSN: 1359-7345
eISSN: 1364-548X
DOI: 10.1039/d4cc01969e
Titel-ID: cdi_rsc_primary_d4cc01969e
Format
–
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