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Methylene-separated bis(thieno[3,2-
b
]pyrroles) and thieno[3,2-
b
]pyrrolopyrroles synthesized for the first time react with NBS and Br
2
to form polymeric materials insoluble in organic solvents. Several synthesized polymers have been investigated as cathode materials in potassium-ion batteries and demonstrated promising electrochemical performances.
The results of the oxidative polymerization of methylene-separated bis-thieno[3,2-
b
]pyrroles and thieno[3,2-
b
]pyrrolopyrroles in the reaction with NBS and Br
2
with the formation of insoluble polymeric materials are discussed, and the electrochemical properties of the polymers are studied.