Details

Autor(en) / Beteiligte

• Nau, Moritz
• Casper, Larissa A
• Haug, Gernot
• Linseis, Michael
• Demeshko, Serhiy
• Winter, Rainer F

Titel

Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2023-04, Vol.52 (15), p.4674-4677

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2023

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing dimerization of the latter and of the one-electron reduced neutral radical. Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing its dimerization.