Details

Autor(en) / Beteiligte

• Nalaoh, Phattananawee
• Jenkins, David M

Titel

Di-triazole boat conformation leads to metal-organic nanotube while chair conformation leads to coordination polymer

Ist Teil von

• CrystEngComm, 2023-09, Vol.25 (35), p.4929-4933

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2023

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Aliphatic-cored di-1,2,4-triazole ligands form both a metal-organic nanotube (MONT) and a coordination polymer upon reaction with silver nitrate. Control of the conformation of the cyclohexane ring between the triazoles determines the reaction outcome where a boat (formed from bicyclo[2.2.2]octane) yields a MONT while a chair (formed from cyclohexane) yields a coordination polymer. Aliphatic-cored di-1,2,4-triazole ligands form both a metal-organic nanotube (MONT) and a coordination polymer upon reaction with silver nitrate.