Details

Autor(en) / Beteiligte

• Paterson, Reece
• Fahy, Luke E
• Arca, Elisabetta
• Dixon, Casey
• Wills, Corinne Y
• Yan, Han
• Griffiths, Anthony
• Collins, Sean M
• Wu, Kejun
• Bourne, Richard A
• Chamberlain, Thomas W
• Knight, Julian G
• Doherty, Simon

Titel

Amine-modified polyionic liquid supports enhance the efficacy of PdNPs for the catalytic hydrogenation of CO to formate

Ist Teil von

• Chemical communications (Cambridge, England), 2023-11, Vol.59 (9), p.1347-13473

Erscheinungsjahr

2023

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid is a remarkably active catalyst for the hydrogenation of CO 2 to formate; the initial TOF of 500 h −1 is markedly higher than either unmodified catalyst or its benzylamine and N , N -dimethylaniline modified counterparts and is among the highest to be reported for a PdNP-based catalyst. Highly efficient hydrogenation of CO 2 to formate catalysed by palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid.