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Sustainable fabrication of ultralong Pb(OH)Br nanowires and their conversion to luminescent CHNHPbBr nanowires
Ist Teil von
Green chemistry : an international journal and green chemistry resource : GC, 2021-10, Vol.23 (2), p.7956-7962
Erscheinungsjahr
2021
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The fabrication of lead halide perovskites involves different types of organic solvents, which are not only harmful to the environment but also expensive. Herein, we present an ultimately green process to prepare CH
3
NH
3
PbBr
3
(MAPbBr
3
) nanowires without using any organic solvents, acids, and alkalis. According to the formula of Pb(OH)Br, only PbBr
2
and water are used to synthesize Pb(OH)Br. Subsequently, the Pb(OH)Br nanowires are converted into MAPbBr
3
nanowires
via
a thermal evaporation technique (
i.e.
, exposing Pb(OH)Br nanowires to MABr vapor). The prepared MAPbBr
3
nanowires show comparable optical properties to those prepared using organic solvents. Such an ultimately green fabrication method can alleviate the environmental concerns and reduce the cost of perovskite commercialization.
Ultralong Pb(OH)Br nanowires can be spontaneously prepared in a pure aqueous solution and then transformed into perovskites with shape preservation.
Sprache
–
Identifikatoren
ISSN: 1463-9262
eISSN: 1463-9270
DOI: 10.1039/d1gc02073k
Titel-ID: cdi_rsc_primary_d1gc02073k
Format
–
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