Details

Autor(en) / Beteiligte

• Donnarumma, P. Rafael
• Frojmovic, Sahara
• Marino, Paola
• Bicalho, Hudson A
• Titi, Hatem M
• Howarth, Ashlee J

Titel

Synthetic approaches for accessing rare-earth analogues of UiO-66

Ist Teil von

• Chemical communications (Cambridge, England), 2021-06, Vol.57 (5), p.6121-6124

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2021

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Rare-earth (RE) analogues of UiO-66 with non-functionalised 1,4-benzenedicarboxylate linkers are synthesised for the first time, and a series of synthetic approaches is provided to troubleshoot the synthesis. RE-UiO-66 analogues are fully characterised, and demonstrate a high degree of crystallinity, high surface area and thermal stability, consistent with the UiO-66 archetype. A series of rare-earth based UiO-66 analogues is synthesised through different approaches with the aid of two different solvents.