Details

Autor(en) / Beteiligte

• Keßler, Sascha
• González-Rubio, Guillermo
• Reinalter, Elrike Rea
• Kovermann, Michael
• Cölfen, Helmut

Titel

Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions temperature-controlled Ni-citrate complexation

Ist Teil von

• Chemical communications (Cambridge, England), 2020-11, Vol.56 (92), p.14439-14442

Erscheinungsjahr

2020

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The citrate-assisted growth of nickel hexacyanoferrate (NiHCF) nanocubes was investigated. Control over the complexation of Ni 2+ ions with citrate at different temperatures enabled fine tuning of the nanocrystal (NC) dimensions and their self-assembly into mesocrystals. Our results introduce new concepts towards the synthesis of NiHCF NCs, potentially applicable to other members of the Prussian blue analogues family. Facile temperature-controlled synthesis of size-tuneable nickel hexacyanoferrate nanocubes to form highly ordered superstructures.