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Valorization of olive mill wastewater for the development of biobased polymer films with antioxidant properties using eco-friendly processes
Ist Teil von
Green chemistry : an international journal and green chemistry resource : GC, 2019-06, Vol.21 (11), p.365-373
Ort / Verlag
Cambridge: Royal Society of Chemistry
Erscheinungsjahr
2019
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The objective of this study was to evaluate the potential of olive mill wastewater (OMWW) for the synthesis of a new active food material. OMWW contains a substantial amount of valuable antioxidant phenols which can be recovered for industrial applications as food additives. The aim of the present study was to synthesize phenolic compound-pectin conjugates by adopting two eco-friendly green procedures: a free radical-induced grafting using the H
2
O
2
/ascorbic acid system and a complexation grafting using CaCl
2
. The antioxidant activities of the selected free phenolic compounds (coumaric acid, caffeic acid, tyrosol, OMWW) and of the phenolic compound-pectin biobased films were investigated with the DPPH assay. The content of polyphenol in OMWW was estimated to be 2 g L
−1
(in gallic acid equivalent), and the free antioxidant activity of OMWW solutions (from 0.2 to 2 g L
−1
of polyphenol (in gallic acid equivalent)) was estimated to be from 60 to 80%. After immobilization processes, the antioxidant activities of each biobased polymer film were efficient and stable for a long contact period. Regarding biobased polymer films using OMWW, the antioxidant activities were estimated to be 61 ± 0.4% and 84 ± 0.8% after 96 h for the CaCl
2
grafting method and the free radical grafting method, respectively.
A green chemistry process to produce eco-friendly antioxidant biobased polymer films from olive mill wastewater.