Details

Autor(en) / Beteiligte

• Sekino, Mio
• Furutachi, Hideki
• Tojo, Rina
• Hishi, Ayumi
• Kajikawa, Hanako
• Suzuki, Takatoshi
• Suzuki, Kaito
• Fujinami, Shuhei
• Akine, Shigehisa
• Sakata, Yoko
• Ohta, Takehiro
• Hayami, Shinya
• Suzuki, Masatatsu

Titel

New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complexElectronic supplementary information (ESI) available: Experimental details of synthesis, and structural, spectroscopic, kinetic, and DFT data. CCDC 1554479. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc04382a

Erscheinungsjahr

2017-08

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A (μ-peroxo)diiron( iii ) complex [Fe 2 (L Ph 4 )(O 2 )(Ph 3 CCO 2 )] 2+ (1-O 2 ) with a dinucleating ligand (L Ph 4 ), generated from the reaction of a carboxylate bridged diiron( ii ) complex [Fe 2 (L Ph 4 )(Ph 3 CCO 2 )] 2+ (1) with dioxygen in CH 2 Cl 2 , provides a diiron( iv )-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation. A diiron( iv )-oxo species ( 1 -oxo) is an essential intermediate in the oxidation reaction initiated by 1 -O 2 .