Details

Autor(en) / Beteiligte

• Godman, N. P
• Barbee, D. B
• Carty, F. B
• McMillen, C. D
• Corley, C. A
• Shurdha, E
• Iacono, S. T

Titel

Synthesis, characterization, and electrochemical properties of new highly processable, hole-transporting fluorocyclic aryl amine polymersElectronic supplementary information (ESI) available: X-ray packing diagrams and crystallographic information for compound 2. CCDC 1479096. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6py00966b

Erscheinungsjahr

2016-09

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Superior hole-transporting mobility and excellent photoconductive properties of aryl amine-containing polymers place them among the most studied materials for optoelectronic applications. Solution processability, however, is a significant limitation to highly arylated polymers particularly for multi-layer organic light emitting devices prepared via spin coating. In this work, the preparation of perfluorocyclopentene aryl ether amine polymers demonstrated improved solubility, but has showed increased thermal stability. Octafluorocyclopentene was used as a coupling agent to prepare a new class of aryl ether amine-containing monomers ultimately yielding high molecular weight, optically transparent step-growth polymers. Herein, this work will present strategic routes for monomer/polymer synthesis, characterization, and viability as a new class of processable coatings or bulk components for the broad area of organic electronics applications. Perfluorocyclopentene (PFCP) aryl ether amine polymers demonstrate excellent solution processing into optically transparent, electrochemically active films as a potential hole-transporting layer material for organic electronic devices.