Details

Autor(en) / Beteiligte

• Xu, Xianhong
• Shi, Zhenyan
• Li, Wenjun

Titel

Organocatalytic 1,3-dipolar [3+3] cycloaddition reaction of 1,2-cyclohexanedione with azides: direct access to highly substituted 1,2,3-triazolesElectronic supplementary information (ESI) available. See DOI: 10.1039/c6nj01083k

Erscheinungsjahr

2016-08

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Enamine-mediated 1,3-dipolar [3+3] cycloaddition reactions of 1,2-cyclohexanedione with azides have been developed. This strategy could generate highly substituted 1,2,3-triazoles in high yields and high levels of regioselectivities. It has been demonstrated that various types of products could be obtained using different organocatalysts and substrates. Enamine-mediated 1,3-dipolar [3+3] cycloaddition reactions of 1,2-cyclohexanedione with azides have been developed. This strategy could generate highly substituted 1,2,3-triazoles in high yields and high levels of regioselectivities. It is demonstrated that various types of products could be obtained with different organocatalysts and substrates.