Details

Autor(en) / Beteiligte

• Roselló-Merino, Marta
• Rama, Raquel J
• Díez, Josefina
• Conejero, Salvador

Titel

Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt(ii), Shimoi-type, η1-BH complexElectronic supplementary information (ESI) available: Experimental section, H2 evolution graphics and X-ray crystallographic data. CCDC 1468913. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc02720b

Erscheinungsjahr

2016-06

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η 1 -BH complexes are key intermediates in the process. The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines.