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Synthesis of reduced graphene oxide-montmorillonite nanocomposite and its application in hexavalent chromium removal from aqueous solutionsElectronic supplementary information (ESI) available. See DOI: 10.1039/c5ra04288g
Erscheinungsjahr
2015-05
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
A reduced graphene oxide-montmorillonite (GCM) nanocomposite has been synthesized
via
a simple solvent method. The results showed that reduced graphene oxide and montmorillonite successfully combined together to form nanocomposites. It indicated that the adsorption of Cr(
vi
) onto GCM nanocomposites was highly pH-dependent with a maximum adsorptive capacity at pH 2.0. The rate of the Cr(
vi
) adsorption is founded to follow pseudo-second-order kinetics and can also be explained by an intraparticle diffusion model. In addition, the experimental data fit well with the Freundlich isotherm model. The adsorptive capacity of Cr(
vi
), as determined from the Langmuir isotherm model, is 12.86 mg g
−1
at 20 °C. Regeneration studies reveal that Cr(
vi
)-loaded GCM can be effectively recycled after the treatment with 0.1 mol L
−1
NaOH solution, confirming the potential of the as-prepared material for practical application.
The combination of Mt and rGO protect rGO from aggregation.
Sprache
Englisch
Identifikatoren
eISSN: 2046-2069
DOI: 10.1039/c5ra04288g
Titel-ID: cdi_rsc_primary_c5ra04288g
Format
–
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