Details

Autor(en) / Beteiligte

• Kulminskaya, Natalia
• Vasa, Suresh Kumar
• Giller, Karin
• Becker, Stefan
• Kwan, Ann
• Sunde, Margaret
• Linser, Rasmus

Titel

Access to side-chain carbon information in deuterated solids under fast MAS through non-rotor-synchronized mixingElectronic supplementary information (ESI) available. See DOI: 10.1039/c5cc07345f

Erscheinungsjahr

2015-12

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• We demonstrate the accessibility of aliphatic 13 C side chain chemical shift sets for solid-state NMR despite perdeuteration and fast MAS using isotropic, non-rotor-synchronized 13 C- 13 C mixing. Combined with amide proton detection, we unambiguously and sensitively detect whole side chain to backbone correlations for two proteins using around 1 mg of sample. MOCCA provides comprehensive solid-state NMR side chain carbon correlations despite perdeuteration and fast sample rotation, thereby inducing minimal power dissipation.