Details

Autor(en) / Beteiligte

• Wo ny, M
• Paw owska, J
• Tomczyk, K. M
• Bilewicz, R
• Korybut-Daszkiewicz, B

Titel

Potential-controlled rotaxane molecular shuttles based on electron-deficient macrocyclic complexesElectronic supplementary information (ESI) available. See DOI: 10.1039/c4cc06718e

Erscheinungsjahr

2014-10

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• This communication reports a novel sandwich-like rotaxane shuttle, which exhibits a unique mode of potential-controlled behaviour. Two dynamic processes occur simultaneously - conformational "unfolding" of the DADA stack accompanies translocation of the ring over the rotaxane's axle. A potential-controlled molecular switch exhibits two different dynamic processes - the translocation of the rotaxane ring occurs simultaneously with folding/unfolding of the axle.