Details

Autor(en) / Beteiligte

• Patil, Dilip V
• Park, Hyun-Sub
• Koo, Jaeyoung
• Han, Jin Wook
• Shin, Seunghoon

Titel

Aerobic oxygenative cleavage of electron deficient C-C triple bonds in the gold-catalyzed cyclization of 1,6-enynesElectronic supplementary information (ESI) available: Optimization study, experimental procedures and characterization data for new compounds. CCDC 933766. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc04153d

Erscheinungsjahr

2014-09

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Gold-catalyzed aerobic oxygenative cleavage of triple bonds that occurs under the ambient pressure of air and at room temperature is reported; radical inhibition tests suggest that oxygenation occurs via a gold-bound metalloradical intermediate. Gold-catalyzed aerobic oxygenative cleavage of triple bonds that occurs under the ambient pressure of air and at room temperature is reported; radical inhibition tests suggest that oxygenation occurs via a gold-bound metalloradical intermediate.