Details

Autor(en) / Beteiligte

• Lao, Zhi-Qi
• Zhong, Wen-He
• Lou, Qing-Hua
• Li, Zhong-Jun
• Meng, Xiang-Bao

Titel

KI-catalyzed imidation of sp3 C-H bond adjacent to amide nitrogen atomElectronic supplementary information (ESI) available. See DOI: 10.1039/c2ob26430g

Erscheinungsjahr

2012-09

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• We have developed a new KI-catalyzed method for the imidation of an sp 3 C-H bond adjacent to an amide nitrogen atom by using TBHP ( tert -butyl hydroperoxide, 70% aqueous solution) as the oxidant. This novel procedure tolerated air and moisture and provided a series of novel products in moderate to excellent yields under mild conditions. A new KI-catalyzed method has been developed for the imidation of an sp 3 C-H bond adjacent to an amide nitrogen atom under mild conditions using TBHP as the oxidant.