Details

Autor(en) / Beteiligte

• Wang, Jianjian
• Ren, Jiawen
• Liu, Xiaohui
• Xi, Jinxu
• Xia, Qineng
• Zu, Yanhong
• Lu, Guanzhong
• Wang, Yanqin

Titel

Direct conversion of carbohydrates to 5-hydroxymethylfurfural using Sn-Mont catalyst

Ist Teil von

• Green chemistry : an international journal and green chemistry resource : GC, 2012-01, Vol.14 (9), p.256-2512

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2012

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• 5-Hydroxymethylfurfural (HMF) is a very important intermediate in the fine chemical industry. This study aims to investigate the direct conversion of glucose or glucose-based carbohydrates, such as sucrose, cellobiose, inulin, starch and cellulose, to HMF by using a Sn-Mont catalyst. With the use of this catalyst, a HMF yield of 53.5% was achieved from glucose in a mono-phase medium of tetrahydrofuran (THF)/dimethylsulfoxide (DMSO) at 160 °C for 3 h. The success of one-step conversion of glucose to HMF is attributed to the Sn-Mont catalyst containing two types of acid sites, Lewis acid and Brønsted acid sites. The former one plays a crucial role in the isomerization of glucose to fructose and the latter one is active in the dehydration of generated fructose to HMF. Furthermore, Sn-Mont catalyst also demonstrated excellent activity in the conversion of disaccharides and polysaccharides and as high as 39.1% HMF was directly obtained from cellulose in a THF/H 2 O-NaCl bi-phasic system. Direct conversion of glucose-based carbohydrates into hydroxymethylfurfural (HMF) via an easily prepared Sn-Mont catalyst with high efficiency and good stability.