Details

Autor(en) / Beteiligte

• Pogna, Eva A. A.
• Tomadin, Andrea
• Balci, Osman
• Soavi, Giancarlo
• Paradisanos, Ioannis
• Guizzardi, Michele
• Pedrinazzi, Paolo
• Mignuzzi, Sandro
• Tielrooij, Klaas-Jan
• Polini, Marco
• Ferrari, Andrea C.
• Cerullo, Giulio

Titel

Electrically Tunable Nonequilibrium Optical Response of Graphene

Ist Teil von

• ACS nano, 2022-03, Vol.16 (3), p.3613-3624

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2022

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The ability to tune the optical response of a material via electrostatic gating is crucial for optoelectronic applications, such as electro-optic modulators, saturable absorbers, optical limiters, photodetectors, and transparent electrodes. The band structure of single layer graphene (SLG), with zero-gap, linearly dispersive conduction and valence bands, enables an easy control of the Fermi energy, E F, and of the threshold for interband optical absorption. Here, we report the tunability of the SLG nonequilibrium optical response in the near-infrared (1000–1700 nm/0.729–1.240 eV), exploring a range of E F from −650 to 250 meV by ionic liquid gating. As E F increases from the Dirac point to the threshold for Pauli blocking of interband absorption, we observe a slow-down of the photobleaching relaxation dynamics, which we attribute to the quenching of optical phonon emission from photoexcited charge carriers. For E F exceeding the Pauli blocking threshold, photobleaching eventually turns into photoinduced absorption, because the hot electrons’ excitation increases the SLG absorption. The ability to control both recovery time and sign of the nonequilibrium optical response by electrostatic gating makes SLG ideal for tunable saturable absorbers with controlled dynamics.