Coordination chemistry reviews, 2021-02, Vol.429, p.213615, Article 213615
2021
Details
- Autor(en) / Beteiligte
- Titel
- A historical perspective on porphyrin-based metal–organic frameworks and their applications
- Ist Teil von
- Coordination chemistry reviews, 2021-02, Vol.429, p.213615, Article 213615
- Ort / Verlag
- Switzerland: Elsevier B.V
- Erscheinungsjahr
- 2021
- Link zum Volltext
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- •Porphyrins are important molecules as enzyme active sites and visible light absorption units.•Porphyrin-based MOFs can isolate and provide access to the inherent properties of porphyrins.•The field of porphyrinic MOFs has evolved from structural explorations to various applications.•Applications of porphyrinic MOFs in catalysis, sensing and biomedicines have been highlighted. Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building blocks for the construction of metal–organic frameworks (MOFs) have rapidly increased due to the ease in which the locations of, and the distances between, the porphyrin units can be controlled in these porous crystalline materials. Porphyrin-based MOFs with atomically precise structures provide an ideal platform for the investigation of their structure–function relationships in the solid state without compromising accessibility to the inherent properties of the porphyrin building blocks. This review will provide a historical overview of the development and applications of porphyrin-based MOFs from early studies focused on design and structures, to recent efforts on their utilization in biomimetic catalysis, photocatalysis, electrocatalysis, sensing, and biomedical applications.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0010-8545eISSN: 1873-3840DOI: 10.1016/j.ccr.2020.213615Titel-ID: cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_7932473