Journal of the American Chemical Society, 2017-10, Vol.139 (39), p.13628-13631
2017
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Details
- Autor(en) / Beteiligte
- Titel
- Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C2 Symmetric Digold Catalysts
- Ist Teil von
- Journal of the American Chemical Society, 2017-10, Vol.139 (39), p.13628-13631
- Ort / Verlag
- American Chemical Society
- Erscheinungsjahr
- 2017
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- The enantioselective intermolecular gold(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C2-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total synthesis of rumphellaone A.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0002-7863eISSN: 1520-5126DOI: 10.1021/jacs.7b07651Titel-ID: cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5679663
- Format
- –
- Schlagworte
- Communication