Details

Autor(en) / Beteiligte

• Skubi, Kazimer L
• Blum, Travis R
• Yoon, Tehshik P

Titel

Dual Catalysis Strategies in Photochemical Synthesis

Ist Teil von

• Chemical reviews, 2016-09, Vol.116 (17), p.10035-10074

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2016

Quelle

MEDLINE

Beschreibungen/Notizen

• The interaction between an electronically excited photocatalyst and an organic molecule can result in the genertion of a diverse array of reactive intermediates that can be manipulated in a variety of ways to result in synthetically useful bond constructions. This Review summarizes dual-catalyst strategies that have been applied to synthetic photochemistry. Mechanistically distinct modes of photocatalysis are discussed, including photoinduced electron transfer, hydrogen atom transfer, and energy transfer. We focus upon the cooperative interactions of photocatalysts with redox mediators, Lewis and Brønsted acids, organocatalysts, enzymes, and transition metal complexes.