Details

Autor(en) / Beteiligte

• Hummel, Joshua R
• Ellman, Jonathan A

Titel

Cobalt(III)-Catalyzed C–H Bond Amidation with Isocyanates

Ist Teil von

• Organic letters, 2015-05, Vol.17 (10), p.2400-2403

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2015

Link zum Volltext

Quelle

MEDLINE

Beschreibungen/Notizen

• The first examples of cobalt­(III)-catalyzed C–H bond addition to isocyanates are described, providing a convergent strategy for arene and heteroarene amidation. Using a robust air- and moisture-stable catalyst, this transformation demonstrates a broad isocyanate scope and good functional-group compatibility and has been performed on gram scale.