Nano letters, 2013-02, Vol.13 (2), p.637-642
2013
Volltextzugriff (PDF)
Details
- Autor(en) / Beteiligte
- Titel
- Tunable Localized Surface Plasmon-Enabled Broadband Light-Harvesting Enhancement for High-Efficiency Panchromatic Dye-Sensitized Solar Cells
- Ist Teil von
- Nano letters, 2013-02, Vol.13 (2), p.637-642
- Ort / Verlag
- Washington, DC: American Chemical Society
- Erscheinungsjahr
- 2013
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- In photovoltaic devices, light harvesting (LH) and carrier collection have opposite relations with the thickness of the photoactive layer, which imposes a fundamental compromise for the power conversion efficiency (PCE). Unbalanced LH at different wavelengths further reduces the achievable PCE. Here, we report a novel approach to broadband balanced LH and panchromatic solar energy conversion using multiple-core–shell structured oxide-metal-oxide plasmonic nanoparticles. These nanoparticles feature tunable localized surface plasmon resonance frequencies and the required thermal stability during device fabrication. By simply blending the plasmonic nanoparticles with available photoactive materials, the broadband LH of practical photovoltaic devices can be significantly enhanced. We demonstrate a panchromatic dye-sensitized solar cell with an increased PCE from 8.3% to 10.8%, mainly through plasmon-enhanced photoabsorption in the otherwise less harvested region of solar spectrum. This general and simple strategy also highlights easy fabrication, and may benefit solar cells using other photoabsorbers or other types of solar-harvesting devices.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1530-6984eISSN: 1530-6992DOI: 10.1021/nl3043823Titel-ID: cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4123315
- Format
- –
- Schlagworte
- Applied sciences, Broadband, Collective excitations (including excitons, polarons, plasmons and other charge-density excitations), Condensed matter: electronic structure, electrical, magnetic, and optical properties, Cross-disciplinary physics: materials science, rheology, Devices, Dyes, Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures, Electronics, Energy, Exact sciences and technology, Harvesting, Materials science, Molecular electronics, nanoelectronics, Nanocrystalline materials, Nanoparticles, Nanoscale materials and structures: fabrication and characterization, Nanostructure, Natural energy, Photovoltaic cells, Photovoltaic conversion, Physics, Plasmonics, Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices, Solar cells, Solar cells. Photoelectrochemical cells, Solar energy, Surface and interface electron states