Angewandte Chemie International Edition, 2012-01, Vol.51 (1), p.204-208
International ed. in English, 2012
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Details
- Autor(en) / Beteiligte
- Titel
- Palladium-Catalyzed Allylic Alkylation of Carboxylic Acid Derivatives: N-Acyloxazolinones as Ester Enolate Equivalents
- Ist Teil von
- Angewandte Chemie International Edition, 2012-01, Vol.51 (1), p.204-208
- Auflage
- International ed. in English
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2012
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- Triple A: A general asymmetric allylic alkylation of ester enolate equivalents at the carboxylic acid oxidation state is reported. N‐Acylbenzoxazolinone‐derived enol carbonates were synthesized and employed in the palladium‐catalyzed alkylation reaction. The imide products were readily converted into a series of carboxylic acid derivatives without loss of enantiopurity.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201105801Titel-ID: cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3517038