Journal of organic chemistry, 2011-12, Vol.76 (23), p.9792-9800
2011
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Details
- Autor(en) / Beteiligte
- Titel
- Synthesis and Reactivity of Bicyclo[3.2.1]octanoid-Derived Cyclopropanes
- Ist Teil von
- Journal of organic chemistry, 2011-12, Vol.76 (23), p.9792-9800
- Ort / Verlag
- Washington, DC: American Chemical Society
- Erscheinungsjahr
- 2011
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- Photochemical oxa-di-π-methane rearrangement of bicyclo[3.2.1]octanoid scaffolds affords multifunctional, donor–acceptor cyclopropanes. A related photochemical reaction of an iminium ether substrate uncovered an unprecedented aza-di-π-methane rearrangement of a β,γ-unsaturated iminium. Donor–acceptor cyclopropanes have been evaluated as substrates for reactions generating several new chemotypes.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0022-3263eISSN: 1520-6904DOI: 10.1021/jo2018922Titel-ID: cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3235415
- Format
- –
- Schlagworte
- Alicyclic compounds, Alicyclic compounds, terpenoids, prostaglandins, steroids, Bridged Bicyclo Compounds - chemical synthesis, Bridged Bicyclo Compounds - chemistry, Chemical reactivity, Chemistry, Crystallography, X-Ray, Cyclopropanes - chemical synthesis, Cyclopropanes - chemistry, Exact sciences and technology, General and physical chemistry, Heterocyclic compounds, Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives, Models, Molecular, Molecular Structure, Organic chemistry, Photochemistry, Physical chemistry of induced reactions (with radiations, particles and ultrasonics), Preparations and properties, Reactivity and mechanisms, Stereoisomerism