Details

Autor(en) / Beteiligte

• Kellner-Rogers, Julian S.
• Wang, Rina
• Lambert, Tristan H.

Titel

Diazene-Catalyzed Oxidative Alkyl Halide–Olefin Metathesis

Ist Teil von

• Organic letters, 2024-02, Vol.26 (5), p.1078-1082

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2024

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The first platform for oxidative alkyl halide–olefin metathesis is described. The procedure employs diazenes as catalysts, which effect the cyclization of alkenyl alkyl halides to generate cyclic olefins and carbonyl products. The synthesis of phenanthrene, coumarin, and quinolone derivatives is demonstrated as well as the potential to apply this strategy to other electrophiles.