Details

Autor(en) / Beteiligte

• Yang, Jing
• Zhan, Shaoqi
• Wang, Linqin
• Yang, Hao
• Duan, Lele
• Fan, Xiaolei
• Liu, Tianqi
• Sun, Licheng

Titel

Adaptive water oxidation catalysis on a carboxylate-sulfonate ligand with low onset potential

Ist Teil von

• Chemical communications (Cambridge, England), 2024-06, Vol.6 (48), p.6162-6165

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2024

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A water oxidation catalyst Ru-bcs (bcs = 2,2′-bipyridine-6′-carboxylate-6-sulfonate) with a hybrid ligand was reported. Ru-bcs utilizes the electron-donating properties of carboxylate ligands and the on-demand coordination feature of sulfonate ligands to enable a low onset potential of 1.21 V vs . NHE and a high TOF over 1000 s −1 at pH 7. The adaptive chemistry uncovered in this work provides new perspectives for developing molecular catalysts with high efficiency under low driving forces. Active site on a hybrid carboxylate-sulfonate ligand for catalytic water oxidation with low onset potential.