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The transformation of (hetero)arene cation radicals has become a powerful tool for the construction of highly functionalized (hetero)arenes. These (hetero)arene cation radicals could be generated under electrochemical, photochemical or chemical oxidation systems. The
in situ
generated (hetero)arene cation radicals can be attacked by various nucleophiles, such as (hetero)aromatics and anions, yielding structurally diverse molecules. Recently, a large number of impressive heteroarene modifications have been designed by this strategy. This review summarizes the advances in heteroarene modification
via
reactions of
in situ
formed (hetero)arene cation radicals, ranging from 2010 to 2020.
This review summarizes the advances in heteroarene modification
via
transformations of
in situ
generated (hetero)arene cation radicals, ranging from 2010 to 2020.