Details

Autor(en) / Beteiligte

• Shi, Taqing
• Xu, Ye
• Zou, Ya-Jing
• Wang, Zhao-Xi

Titel

Synthesis, structure and magnetic properties of copper() azide

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2019-08, Vol.48 (3), p.11186-1119

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A novel azide-bridged copper compound without an auxiliary ligand has been synthesized and characterized by single-crystal diffraction analysis. The compound consists of 1D double chains with end-on (EO) azide bridges. Furthermore, the neighboring chains are connected by weak coordination bonds, which leads to the formation of a 3D architecture. Low-temperature magnetic measurements reveal that antiferromagnetic interactions are dominant, with concomitant spin-canted antiferromagnetism. A novel 3D copper( ii ) azide built from 1D double chains with EE azide bridges has been synthesized by hydrothermal reaction. The magnetic analyses reveal that antiferromagnetic interactions are dominant with concomitant spin-canted antiferromagnetism.