Details

Autor(en) / Beteiligte

• Prosa, Mario
• Benvenuti, Emilia
• Pasini, Mariacecilia
• Giovanella, Umberto
• Bolognesi, Margherita
• Meazza, Lorenzo
• Galeotti, Francesco
• Muccini, Michele
• Toffanin, Stefano

Titel

Organic light-emitting transistors with simultaneous enhancement of optical power and external quantum efficiency via conjugated polar polymer interlayer

Ist Teil von

• ACS applied materials & interfaces, 2018-07

Ort / Verlag

United States

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Organic light-emitting transistors (OLETs) show the fascinating combination of electrical switching characteristics and light generation capability. However, to ensure an effective device operation, efficient injection of charges into the emissive layer is required. The introduction of solution-processed conjugated polyelectrolytes (CPEs) films at the emissive layer/electrode interface represents a promising strategy to improve the electron-injection process by dipole formation. However, their use in optoelectronic devices involves also some limitations due to the ionic nature of CPEs. In this context, neutral conjugated polar polymers (CPPs) represent a valid alternative to CPEs since the conjugated backbones of CPPs are functionalized with polar non-ionic side groups, thus avoiding ion-dependent drawbacks. By introducing a layer of polyfluorene containing phosphonate groups (PF-EP) underneath the metal electrodes, we here demonstrate a substantial improvement of the electron injection properties into the OLET emissive layer and, accordingly, a more than twofold increased light power and a five-times-higher external quantum efficiency of p-type OLETs in comparison with reference devices without any interlayer. The great benefit of using a transparent glass substrate allowed to selectively investigate the morphological and photoluminescent characteristics of both CPE- and CPP-buried interlayers within complete OLETs by means of an optical scanning probe technique. This, together with a thorough optoelectronic characterization of the figures of merit of working light-emitting devices allowed to disclose the origin of the improved optical performance of CPP-based devices as well as the operation mechanisms of the investigated interlayer in the corresponding OLETs.