Details

Autor(en) / Beteiligte

• del Río, José C
• Prinsen, Pepijn
• Rencoret, Jorge
• Nieto, Lidia
• Jiménez-Barbero, Jesús
• Ralph, John
• Martínez, Ángel T
• Gutiérrez, Ana

Titel

Structural Characterization of the Lignin in the Cortex and Pith of Elephant Grass (Pennisetum purpureum) Stems

Ist Teil von

• Journal of agricultural and food chemistry, 2012-04, Vol.60 (14), p.3619-3634

Ort / Verlag

Washington, DC: American Chemical Society

Erscheinungsjahr

2012

Quelle

MEDLINE

Beschreibungen/Notizen

• The structure of the lignin in the cortex and pith of elephant grass (Pennisetum purpureum) stems was studied both in situ and in isolated milled “wood” lignins by several analytical methods. The presence of p-coumarate and ferulate in the cortex and pith, as well as in their isolated lignins, was revealed by pyrolysis in the presence of tetramethylammonium hydroxide, and by 2D NMR, and indicated that ferulate acylates the carbohydrates while p-coumarate acylates the lignin polymer. 2D NMR showed a predominance of alkyl aryl ether (β–O–4′) linkages (82% of total interunit linkages), with low amounts of “condensed” substructures, such as resinols (β–β′), phenylcoumarans (β–5′), and spirodienones (β–1′). Moreover, the NMR also indicated that these lignins are extensively acylated at the γ-carbon of the side chain. DFRC analyses confirmed that p-coumarate groups acylate the γ-OHs of these lignins, and predominantly on syringyl units.