Details

Autor(en) / Beteiligte

• Mowat, John P S
• Seymour, Valerie R
• Griffin, John M
• Thompson, Stephen P
• Slawin, Alexandra M Z
• Fairen-Jimenez, David
• Düren, Tina
• Ashbrook, Sharon E
• Wright, Paul A

Titel

A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2012-04, Vol.41 (14), p.3937-3941

Ort / Verlag

England

Erscheinungsjahr

2012

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO(2) adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO(2).