Angewandte Chemie (International ed.), 2011-12, Vol.50 (51), p.12184-12188
International ed. in English, 2011
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Details
- Autor(en) / Beteiligte
- Titel
- Au-Pd Core-Shell Nanoparticles Catalyze Suzuki-Miyaura Reactions in Water through Pd Leaching
- Ist Teil von
- Angewandte Chemie (International ed.), 2011-12, Vol.50 (51), p.12184-12188
- Auflage
- International ed. in English
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2011
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Away from the surface: Novel nanoparticles (NPs) consisting of 16 nm Au cores surrounded by Pd shells of various thicknesses catalyze Suzuki–Miyaura cross‐coupling reactions in water at room temperature. NPs having shells of two to five Pd monolayers thick exhibit the highest catalytic activity. Catalysis was attributed to the leaching of Pd species from the NPs through the synergistic action of the carbonate base and the arylboronic acid.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201103465Titel-ID: cdi_proquest_miscellaneous_911945184
- Format
- –
- Schlagworte
- Carbonates, Catalysis, Catalytic activity, electrochemistry, Gold, Leaching, Monolayers, Nanoparticles, Palladium, Pd-leaching mechanism, SERS, Surface chemistry, Suzuki-Miyaura reaction