Details

Autor(en) / Beteiligte

• Saha, Debasree
• Saha, Amit
• Ranu, Brindaban C.

Titel

Remarkable influence of substituent in ionic liquid in control of reaction: simple, efficient and hazardous organic solvent free procedure for the synthesis of 2-aryl benzimidazoles promoted by ionic liquid, [pmim]BF4

Ist Teil von

• Green chemistry : an international journal and green chemistry resource : GC, 2009-01, Vol.11 (5), p.733-737

Erscheinungsjahr

2009

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A simple and efficient procedure for the synthesis of 2-substituted benzimidazoles has been developed by a one-pot reaction of o-phenylenediamine with aromatic aldehydes in the presence of an ionic liquid, 1-methyl-3-pentylimidazolium tetrafluoroborate, [pmim]BF4 at room temperature in open air without any organic solvent. The ionic liquid is recycled. A remarkable influence of the substituent on the imidazolium unit of the ionic liquid on the outcome of the reaction is observed.