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MoS2 Nanoplates Consisting of Disordered Graphene-like Layers for High Rate Lithium Battery Anode Materials
Ist Teil von
Nano letters, 2011-11, Vol.11 (11), p.4826-4830
Ort / Verlag
Washington, DC: American Chemical Society
Erscheinungsjahr
2011
Quelle
MEDLINE
Beschreibungen/Notizen
MoS2 nanoplates, consisting of disordered graphene-like layers, with a thickness of ∼30 nm were prepared by a simple, scalable, one-pot reaction using Mo(CO)6 and S in an autoclave. The product has a interlayer distance of 0.69 nm, which is much larger than its bulk counterpart (0.62 nm). This expanded interlater distance and disordered graphene-like morphology led to an excellent rate capability even at a 50C (53.1 A/g) rate, showing a reversible capacity of 700 mAh/g. In addition, a full cell (LiCoO2/MoS2) test result also demonstrates excellent capacity retention up to 60 cycles.