A Formal High Oxidation State Inverse-Sandwich Diuranium Complex: A New Route to f-Block-Metal Bonds
International ed. in English, 2011
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Details
- Autor(en) / Beteiligte
- Titel
- A Formal High Oxidation State Inverse-Sandwich Diuranium Complex: A New Route to f-Block-Metal Bonds
- Ist Teil von
- Angewandte Chemie (International ed.), 2011-10, Vol.50 (44), p.10388-10392
- Auflage
- International ed. in English
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2011
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- UCo bond: Reduction of [U(TsXy)(Cl)(thf)] [1; TsXy=HC(SiMe2NAr)3; Ar=3,5‐Me2C6H3] with KC8 in toluene afforded the new arene‐bridged diuranium complex 2, whereas reduction of 1 in aliphatic hydrocarbons resulted in CN bond activation and formation of an imido‐aryl complex, which exhibits an unusual ferromagnetic interaction between the two uranium centers. The synthetic utility of 2 was demonstrated by the first synthesis of a UCo complex, [U(TsXy)Co(CO)3(PPh3)] (3).
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201104110Titel-ID: cdi_proquest_miscellaneous_899129196
- Format
- –
- Schlagworte
- arenes, density functional theory, metal-metal bonds, redox reactivity, uranium