Details

Autor(en) / Beteiligte

• González-Gallardo, Sandra
• Jancik, Vojtech
• Delgado-Robles, Alma A
• Moya-Cabrera, Mónica

Titel

Cyclic Alumosiloxanes and Alumosilicates: Exemplifying the Loewenstein Rule at the Molecular Level

Ist Teil von

• Inorganic chemistry, 2011-05, Vol.50 (10), p.4226-4228

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2011

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The cyclic alumosiloxane [{LAl(μ-O)(Ph2Si)(μ-O)}2] (3) and alumosilicate [{LAl(μ-O){(tBuO)2Si}(μ-O)}2] (4) were obtained by reaction of the appropriate R2Si(OH)2 precursor (R = Ph, O t Bu) with [{LAl(H)}2(μ-O)] (1), providing a nice illustration of the Loewenstein rule at work at the molecular level.