Details

Autor(en) / Beteiligte

• Nickl, Claudia
• Eichele, Klaus
• Joosten, Dominik
• Langer, Thorsten
• Schappacher, Falko M.
• Pöttgen, Rainer
• Englert, Ulli
• Wesemann, Lars

Titel

1,1,1-Tris(distanna-closo-dodecaborate)stannate: A Tripodal Tin Ligand

Ist Teil von

• Angewandte Chemie (International ed.), 2011-06, Vol.50 (25), p.5766-5769

Auflage

International ed. in English

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2011

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Tin tripod: Starting from 1,2‐distanna‐closo‐dodecaborate and tin(II) chloride, the first tripodal tin ligand was prepared. It is made up of three clusters and one central tin atom that build a frame of seven tin atoms. The coordination ability is illustrated by reaction with [Cu(CH3CN)4]PF6: a binuclear copper complex is formed surrounded by two Sn7 ligands (see picture).