Details

Autor(en) / Beteiligte

• Aggarwal, Varinder K
• Binanzer, Michael
• de Ceglie, M. Carolina
• Gallanti, Maddalena
• Glasspoole, Ben W
• Kendrick, Stephanie J. F
• Sonawane, Ravindra P
• Vázquez-Romero, Ana
• Webster, Matthew P

Titel

Asymmetric Synthesis of Tertiary and Quaternary Allyl- and Crotylsilanes via the Borylation of Lithiated Carbamates

Ist Teil von

• Organic letters, 2011-03, Vol.13 (6), p.1490-1493

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2011

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Tertiary allyl- or crotylsilanes have been prepared in high er and dr via the lithiation−borylation reaction of alkyl carbamates with silaboronates. Using a related strategy, quaternary allylsilanes could be accessed in similarly high er.