Journal of the American Chemical Society, 2011-02, Vol.133 (7), p.2112-2115
2011
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Details
- Autor(en) / Beteiligte
- Titel
- Synthesis of NHC Complexes by Oxidative Addition of 2-Chloro-N-methylbenzimidazole
- Ist Teil von
- Journal of the American Chemical Society, 2011-02, Vol.133 (7), p.2112-2115
- Ort / Verlag
- United States: American Chemical Society
- Erscheinungsjahr
- 2011
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- The oxidative addition of 2-chloro-N-methylbenzimdazole to complexes of type [M(PPh3)4] yields after N-protonation compounds with NH,NMe-substituted NHC ligands. For M = Pd complex compound trans-[3]BF4 was obtained, while the oxidative addition for M = Pt yielded a mixture of cis-[4]BF4 (major) and trans-[4]BF4 (minor).
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0002-7863eISSN: 1520-5126DOI: 10.1021/ja110634hTitel-ID: cdi_proquest_miscellaneous_858115310
- Format
- –