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The Doppler broadening of individual γ-ray lines was measured with a high purity germanium detector in JET plasma experiments. High-resolution γ-ray spectrometry of nuclear reactions between energetic D, 3 He and 4 He ions accelerated by ion cyclotron resonance heating and main plasma impurities such as carbon and beryllium has been used. The nuclear reactions giving rise to γ-rays have been identified and an effective temperature of the heated ions has been obtained in JET discharges. This technique could be used for fast ion and fusion alpha-particle studies in ITER.