Archives of biochemistry and biophysics, 1984-09, Vol.233 (2), p.772-775
1984
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Details
- Autor(en) / Beteiligte
- Titel
- Studies of the reactivity of HO2/O2- with unsaturated hydroperoxides in ethanolic solutions
- Ist Teil von
- Archives of biochemistry and biophysics, 1984-09, Vol.233 (2), p.772-775
- Ort / Verlag
- San Diego, CA: Elsevier
- Erscheinungsjahr
- 1984
- Quelle
- Elsevier Journal Backfiles on ScienceDirect (DFG Nationallizenzen)
- Beschreibungen/Notizen
- A study of the reactivity of HO2/O2- with unsaturated hydroperoxides/peroxides was carried out in a stopped-flow spectrophotometer equipped with an O2--generating plasma lamp. The results show that, in 80% aqueous ethanol solution containing either 0.05 M H2SO4 (for HO2 studies) or 0.005 M KOH (for O2- studies), these oxy-radicals do not react with oleic acid hydroperoxide, linoleic acid hydroperoxide, 1-hydroperoxy-2-cyclooctene, and tert-butyl allyl peroxide. These findings are discussed in the light of conflicting evidence concerning the reaction of HO2/O2- with organic hydroperoxides/peroxides.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0003-9861eISSN: 1096-0384DOI: 10.1016/0003-9861(84)90505-8Titel-ID: cdi_proquest_miscellaneous_81278220
- Format
- –
- Schlagworte
- Biological and medical sciences, Chemical Phenomena, Chemistry, Ethanol, Fundamental and applied biological sciences. Psychology, Hydrogen Peroxide, Linoleic Acids, Lipid Peroxides, Mechanisms. Catalysis. Electron transfer. Models, Molecular biophysics, Peroxides, Physical chemistry in biology, Superoxides