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Aqueous phase synthesis and fluorescence properties of inverted core/shell ZnSe/CdSe nanocrystals
Ist Teil von
Wuhan University journal of natural sciences, 2010-08, Vol.15 (4), p.320-324
Ort / Verlag
Heidelberg: Wuhan University
Erscheinungsjahr
2010
Quelle
Springer journals
Beschreibungen/Notizen
We report a facile aqueous phase synthesis for preparing water-soluble inverted core/shell ZnSe/CdSe semiconductor nanocrystals. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and their optical properties were investigated by using UV-vis-NIR spectrophotometer and fluorescence spectrophotometer. The results indicate that the synthesized ZnSe/CdSe nanocrystals are inverted core/shell structure with diameter of about 5 nm. Furthermore, their absorption band-edge is red-shifted with the growth of CdSe shell; correspondingly, their emission wavelength can be tuned from 460 nm to 604 nm.